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 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">Russian Journal of Biological Physics and Chemisrty</journal-id>
   <journal-title-group>
    <journal-title xml:lang="en">Russian Journal of Biological Physics and Chemisrty</journal-title>
    <trans-title-group xml:lang="ru">
     <trans-title>АКТУАЛЬНЫЕ ВОПРОСЫ БИОЛОГИЧЕСКОЙ ФИЗИКИ И ХИМИИ</trans-title>
    </trans-title-group>
   </journal-title-group>
   <issn publication-format="print">2499-9962</issn>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="publisher-id">54193</article-id>
   <article-categories>
    <subj-group subj-group-type="toc-heading" xml:lang="ru">
     <subject>МОЛЕКУЛЯРНАЯ БИОФИЗИКА И ФИЗИКА БИОМОЛЕКУЛ</subject>
    </subj-group>
    <subj-group subj-group-type="toc-heading" xml:lang="en">
     <subject>MOLECULAR BIOPHYSICS AND PHYSICS OF BIOMOLECULES</subject>
    </subj-group>
    <subj-group>
     <subject>МОЛЕКУЛЯРНАЯ БИОФИЗИКА И ФИЗИКА БИОМОЛЕКУЛ</subject>
    </subj-group>
   </article-categories>
   <title-group>
    <article-title xml:lang="en">Measuring self-association of Pt-complexes by 195Pt NMR</article-title>
    <trans-title-group xml:lang="ru">
     <trans-title>Исследование самоассоциации платиносодержащих молекул методом ЯМР спектроскопии</trans-title>
    </trans-title-group>
   </title-group>
   <contrib-group content-type="authors">
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Яковлев</surname>
       <given-names>Д А</given-names>
      </name>
      <name xml:lang="en">
       <surname>Yacovlev</surname>
       <given-names>D A</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-1"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Баранов</surname>
       <given-names>Д Ю</given-names>
      </name>
      <name xml:lang="en">
       <surname>Baranov</surname>
       <given-names>D U</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-2"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Пронозин</surname>
       <given-names>А Ю</given-names>
      </name>
      <name xml:lang="en">
       <surname>Pronozin</surname>
       <given-names>A U</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-3"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Лантушенко</surname>
       <given-names>А О</given-names>
      </name>
      <name xml:lang="en">
       <surname>Lantushenko</surname>
       <given-names>A O</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-4"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Кожевников</surname>
       <given-names>Д Н</given-names>
      </name>
      <name xml:lang="en">
       <surname>Kogevnikov</surname>
       <given-names>D N</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-5"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Ельцов</surname>
       <given-names>О С</given-names>
      </name>
      <name xml:lang="en">
       <surname>Eltsov</surname>
       <given-names>O S</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-6"/>
    </contrib>
   </contrib-group>
   <aff-alternatives id="aff-1">
    <aff>
     <institution xml:lang="ru">Севастопольский государственный университет</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Sevastopol State University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-2">
    <aff>
     <institution xml:lang="ru">Севастопольский государственный университет</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Sevastopol State University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-3">
    <aff>
     <institution xml:lang="ru">Севастопольский государственный университет</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Sevastopol State University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-4">
    <aff>
     <institution xml:lang="ru">Севастопольский государственный университет</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Sevastopol State University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-5">
    <aff>
     <institution xml:lang="ru">Нортумбрийский университет</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Northumbria University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-6">
    <aff>
     <institution xml:lang="ru">Уральский федеральный университет имени первого Президента России Б.Н. Ельцина</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Ural Federal University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <pub-date publication-format="print" date-type="pub" iso-8601-date="2017-06-25T20:22:29+03:00">
    <day>25</day>
    <month>06</month>
    <year>2017</year>
   </pub-date>
   <pub-date publication-format="electronic" date-type="pub" iso-8601-date="2017-06-25T20:22:29+03:00">
    <day>25</day>
    <month>06</month>
    <year>2017</year>
   </pub-date>
   <volume>2</volume>
   <issue>1</issue>
   <fpage>365</fpage>
   <lpage>368</lpage>
   <history>
    <date date-type="received" iso-8601-date="2017-06-20T20:22:29+03:00">
     <day>20</day>
     <month>06</month>
     <year>2017</year>
    </date>
    <date date-type="accepted" iso-8601-date="2017-06-20T20:22:29+03:00">
     <day>20</day>
     <month>06</month>
     <year>2017</year>
    </date>
   </history>
   <self-uri xlink:href="https://rusjbpc.ru/en/nauka/article/54193/view">https://rusjbpc.ru/en/nauka/article/54193/view</self-uri>
   <abstract xml:lang="ru">
    <p>Методом ЯМР спектроскопии в растворе CDCl3 была изучена агрегация нейтрального циклометаллированного платиносодержащего комплекса типа СNN. Исследования показывают, что 195Pt NMR может использоваться для количественной оценки агрегации и как следствие применим для большинства платиносодержащих комплексов. Техника двумерной гетероядерной корреляции 1H-195Pt повышает чувствительность эксперимента и позволяет измерять химические сдвиги 195Pt при концентрациях до 1мМ. Было обнаружено, что с повышением концентрации ароматические протоны испытывают экранирование, тогда как ядра платины напротив деэкранируются.</p>
   </abstract>
   <trans-abstract xml:lang="en">
    <p>Neutral cyclometallated Pt complex of CNN type was prepared and its self-aggregation in CDCl3 solution was studied by NMR dilution method. It was shown that 195Pt NMR can be used to quantify aggregation and therefore be potentially applied to many other Pt complexes. Two-dimensional HMBC 1H-195Pt technique increases sensitivity of experiment and allowed recording 195Pt chemical shift values at concentration as low as 1mM and it was observed that opposite to shielding of aromatic protons, Pt nucleus is deshielded upon increase of concentration.</p>
   </trans-abstract>
   <kwd-group xml:lang="ru">
    <kwd>ЯМР спектроскопия</kwd>
    <kwd>Pt комплекс</kwd>
    <kwd>самоассоциация</kwd>
   </kwd-group>
   <kwd-group xml:lang="en">
    <kwd>Pt complex</kwd>
    <kwd>195Pt NMR</kwd>
    <kwd>self-aggregation</kwd>
   </kwd-group>
  </article-meta>
 </front>
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 <back>
  <ref-list>
   <ref id="B1">
    <label>1.</label>
    <citation-alternatives>
     <mixed-citation xml:lang="ru">Suleymanova A.F., Eltsov O.S., Kozhevnikov D.N., Lantushenko A.O., Evstigneev M.P., Kozhevnikov V.N. СhemistrySelect, 2017, vol. 2, p. 3353.</mixed-citation>
     <mixed-citation xml:lang="en">Suleymanova A.F., Eltsov O.S., Kozhevnikov D.N., Lantushenko A.O., Evstigneev M.P., Kozhevnikov V.N. ShemistrySelect, 2017, vol. 2, p. 3353.</mixed-citation>
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   </ref>
  </ref-list>
 </back>
</article>
