Russian Journal of Biological Physics and Chemisrty Russian Journal of Biological Physics and Chemisrty АКТУАЛЬНЫЕ ВОПРОСЫ БИОЛОГИЧЕСКОЙ ФИЗИКИ И ХИМИИ 2499-9962 54236 Общая биофизика General biophysics Общая биофизика ON THE INTERACTION OF WATER WITH HYDROPHILIC SURFACES К ВОПРОСУ О ВЗАИМОДЕЙСТВИИ ВОДЫ С ГИДРОФИЛЬНЫМИ ПОВЕРХНОСТЯМИ Яхно Т. А. Yakhno T. A. yakhta13@gmail.com Яхно В. Г. Yakhno V. G. ФИЦ Институт прикладной физики Российской Академии Наук Нижний Новгород Россия FRC Institute of Applied Physics Russian Academy of Science Nizhny Novgorod Russian Federation ФИЦ Институт прикладной физики Российской Академии Наук Нижний Новгород Россия FRC Institute of Applied Physics Russian Academy of Science Nizhny Novgorod Russian Federation 25 03 2018 25 03 2018 3 1 9 18 20 03 2018 20 03 2018 https://rusjbpc.ru/en/nauka/article/54236/view

Кратко рассмотрена история исследования взаимодействия воды с гидрофильными поверхностями, включая феномен «поливоды». На примере стеклянных предметов, погруженных в воду, прослежено образование «зоны исключения» (EZ), подтверждено снижение концентрации ионов в пристеночном слое и его жидкокристаллическая структура. Показано, что EZ образуется как при освещении, так и в темноте. Рассматриваются молекулярные механизмы формирования и роста EZ, в основе которых лежит физическая адсорбция, обусловленная снижением свободной энергии системы. Присутствие в воде катионов существенно влияет на формирование EZ. Характер влияния определяется размером катиона (плотностью поверхностных зарядов). На основе данных литературы и собственных результатов обсуждается единая природа образования гидратных оболочек вокруг ионов и формирования EZ.

The history of the study of the interaction of water with hydrophilic surfaces, including the phenomenon of "polywater", is briefly considered. On the example of glass objects immersed in water, the formation of an "exclusion zone" (EZ) was traced, the decrease in the ion concentration in the EZ and its liquid crystal structure was confirmed. It is shown that EZ is formed both under illumination and in darkness. Molecular mechanisms of formation and growth of EZ are considered, which are based on physical adsorption caused by a decrease in the free energy of the system. The presence of cations in water significantly influences the formation of EZ. The nature of the effect is determined by the size of the cation (the density of surface charges). Based on literature data and the results of the study, the unified nature of the formation of hydrated shells around ions and the organization of EZ is discussed.

 вода гидрофильная поверхность EZ физическая адсорбция гидратация стекла water hydrophilic surfaces EZ physical adsorption glass hydration

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