The uniform kinetic model for a biosynthesis of monoterpenes by analysis of their comprehensive quality and quantitative capacity in essential oil of some representatives of kind Artemisia is founded. Mechanisms of single-step processes of an interlinking between the isoprene, carbocation of dimethylallyl and carbocation of isopentyl, which explain the formation of hydrocarbonate carcass for all kinds of acyclic, mono- and bicyclic monoterpenes are presented. The mathematical model of their accumulation depending on vegetative phases is founded. The new method to define kinetic constants in processes of a natural biosynthesis of monoterpenes in a current is developed due to the combination of mathematical modelling of biochemical processes with received experimental data about the accumulation of acyclic, mono- and bicyclic monoterpenes in various vegetative phases. Numerical values of kinetic constants in the biosynthesis of monoterpenes for each investigated vegetative kind which characterize own dynamics of their reproduction in all types of monoterpenes are determined.
Artemisia, a biosynthesis of monoterpenes, a kinetic model, kinetic constants
1. Hodakov G.V., Kotikov I.V. Komponentnyy sostav efirnogo masla Artemisia taurica. Himiya prirod. soedin., 2008, № 2, c. 205-206. [Khodakov G.V., Kotikov I.V. Component composition of essential oil from Artemisia taurica. Khimiya Prirodnykh Soedinenii, 2008, no. 2, pp. 205-206. (In Russ.)]
2. Hodakov G.V., Kotikov I.V., Pankoveckiy V.N. Komponentnyy sostav efirnogo masla Artemisia abrotanum i Artemisia dracunculus. Himiya prirod. soedin., 2009, № 6, c. 755-758. [Khodakov G.V., Kotikov I.V., Pankovetski V.N. Component composition of essential oil from Artemisia taurica. Khimiya Prirodnykh Soedinenii, 2009, no. 6, pp. 755-758. (In Russ.)]
3. Hodakov G.V., Kotikov I.V. Komponentnyy sostav efirnogo masla Artemisia annua i Artemisia scoparia. Himiya prirod. soedin., 2009, № 6, c. 759-761. [Khodakov G.V., Kotikov I.V. Component composition of essential oil from Artemisia annua i Artemisia scoparia. Khimiya Prirodnykh Soedinenii, 2008, no. 2, pp. 759-761. (In Russ.)]
4. Loloyko A.A., Petrishina N.N., Nevkrytaya N.V., Marchenko M.P. Osobennosti biosinteza efirnogo masla v semennom potomstve polyni estragon (Artemisia dracunculus). Ekosistemy, ih optimizaciya i ohrana, 2011, vyp. 4, c. 116-122. [Loloiko A.A., Petrishina N.N., Nevkritaya N.V., Martchenko M.P. Features of biosynthesis of essential oil in the seed progeny of Artemisia dracunculus. Ecosystems, their optimization and protection, 2011, vol. 4, pp. 116-122. (In Russ.)]
5. Kintya P.K., Fadeev Yu.M., Akimov Yu.A. Terpenoidy rasteniy. Kishinev, Shtiinca, 1990, 152 s. [Kintya P.K., Fadeev Yu.M., Akimov Yu.A. Terpenoids of plants, Kishinev, 1990, 152 p. (In Russ.)]
6. Polyanskaya E.V., Korolyuk E.A., Tkachev A.V. Sostav efirnogo masla iz polyni Glauca iz Zapadnoy Sibiri. Himiya prirod. soedin., 2007, № 5, c. 544-547. [Polyanski E.V., Korolyuk E.A., Tkatchev A.V. The composition of essential oil from Artemisia Glauca from Western Siberia. Khimiya Prirodnykh Soedinenii, 2007, no. 5, pp. 544-547. (In Russ.)]
7. Shmid R.,. Sapunov V.N. Neformal'naya kinetika. V poiskah putey himicheskih reakciy. M.: Mir, 1985, 264 s. [Shmit R., Sapunov V.N. Informal kinetics. In search of ways of chemical reactions. M., 1985, 264 p. (In Russ.)]
8. Rohmer M. The discovery of a mevalonate-independent pathway for isoprenoid biosynthesis in bacteria, algae and higher plants. Nat. Prod. Rep., 1999, vol. 16, pp. 565-574.
9. Porter J.W. Enzymatic synthesis of carotenoid and related compounds. Pure Appl. Chem., 1969, vol. 20, pp. 449-481.
10. Britton G. Carotenoids: Biosynthesis and Metabolism, 1998, vol. 3, 414 p.
11. Barton D., Ollis W.D. The Synthesis and Reactions of Organic Compounds. Biological compounds, 1979, vol. 5, 736 p.
12. D'yakonov V.P. Sistema MathCad: spravochnik. M.: Radio i svyaz', 1993, 128 s. [ (In Russ.)]
13. Branovickaya S.V., Medvedev R.V.,. Fialkov Yu.Ya. Vychislitel'naya matematika v himii i himicheskoy tehnologii. K.: Vischa shkola, 1986, 216 s. [Bronevitskaja S.V., Medvedev R.V., Fialkov Yu.Ja. Calculus mathematics in Chemistry and Chemical Technology. K., 1986, 216 p. (In Russ.)]
14. MathCad 6.0 Plus. Finansovye, inzhenernye i nauchnye raschety v srede Windows 95. M., Filin', 1997, 712 s. [Mathcad. User's Guide MathCad 6.0, Mathcad PLUS 6.0. M., Filin, 1997, 712 p. (In Russ.)]
15. Larsen R.U. Inzhenernye raschety v Excel. M.: Vil'yams, 2002, 544 s. [Larsen R.W. Engineering with Excel, M., 2002, 544 p. (In Russ.)]
