For the purpose of development and studying of the porphyrines aggregated forms in the stabilized state optical properties (optical absorption and fluorescence) of the films of 5,10,15,20-tetraphenylporphyrin monomer and H- and J-agregates and also their current voltage characteristics are investigated. Various spectral and electric characteristics of tetraphenylporphyrin with different type of aggregation are received. According to their characteristics J- agregates are close to monomer of tetraphenylporphyrin. For the films with J-agregates fluorescence and an electric response which aren't observed in the case of films with H-agregates are registered. These data and also the existence of absorption in red region of spectrum do J- agregates of tetraphenylporphyrin perspective materials during creation of film systems for photovoltaics, photocatalysis and photodynamic processes. An opportunity to change structure of such films allows receiving thin films of organic materials with predetermined properties and a wide range of possibilities.
-aggregates, J-aggregates spectral characteristics, optical absorption, fluorescence, current voltage characteristics
1. Mamardashvili G.M., Mamardashvili N.Zh., Koyfman O.I. Supramolekulyarnye kompleksy porfirinov. Uspehi himii, 2005, t. 74, № 8, s. 839-855. [Mamardashvili G.M., Mamardashvili N.Zh., Koifman O.I. Supramolecular porphyrin complexes. Russian Chemical Reviews, 2005, vol. 74, no. 8, pp. 765-780. (In Russ.)]
2. Romanov N.M., Zaharova I.B. Sostav i struktura tonkih plenok na osnove metallporfirinovyh kompleksov. Nauchno-tehnicheskie vedomosti SPbGPU. Fizichesko-matematicheskie nauki, 2016, № 2 (242), s. 9-18. [Romanov N.M., Zakharova I.B., Structure and structure of thin films based on metallporphyrines complexes. Nauchno-technicheskie vedomosti SPbGPU. Physico-mathematical. sciences, 2016, no. 2 (242), pp. 9-18. (In Russ.)]
3. Yackov N.N., Apanasovich V.V., Kuhorst R.B.M., vann Huk A., Shafema T.Y. Elektronnye spektry i kinetitka polyarizacii fluorescencii tonkih plenok Zn-porfirinov, Zhurnal Prikladnoy spektroskopii, 2003, t. 70, № 3, s. 335-339. [Yatskov N.N., Apanasovich V.V., Koehorst R.B.M., Van Hoek A., Schaafsma T.J., Electronic spectra and fluorescence polarization kinetics of thin Zn-porphyrine films. Journal of Applied Spectrosopy, 2003, vol. 70, no. 3, pp. 372-377. (In Russ.)]
4. Kim B., Leonard J.J., Longo F.R. A mechanistic study of the synthesis and spectral properties of meso- tetraphenylporphyrin. J. Am. Chem. Soc., 1972, vol. 94, no. 11, pp. 3986-3992.
5. Nikolenko L.M, Ivanchihina A.V. Osobennosti formirovaniya J-agregatov cianinovyh krasiteley v rastvorah obratnyh micell AOT/voda/geksan. Himiya vysokih energiy, 2010, t. 44, № 6, s. 546-554. [Nikolenko L.M., Ivanchikhina A.V., Specifics of the formation of J-aggregates of cyanine dyes in solutions of AOT/water/hexane reverse micelles. High Energy Chemistry, 2010, vol. 44, no. 6, pp. 511-519. (In Russ.)]
6. Muenter A.A., Brumbaugh D.V., Apolito J.J., Horn L.A., Spano F.c., Mukamel S. Size Dependence of Excited- State Dynamics for J-Aggregates at AgBr Interfaces. J. Phys. Chem., 1992, vol. 96, pp. 2783-2790.
7. Garcia Jimunez F., Khramov M.I., Sanchez-Obregon R., Collera O. Chem. Phys. Lett., 2000, vol. 331, no. 1, pp. 42-46.
8. Lastovoy A.P. Vliyanie mezhmolekulyarnyh vzaimodeystviy na spektral'nye i fotohimicheskie svoystva proizvodnyh tetraazahlorina. Diss. … kand. him. nauk. Moskva, 2014. [Lastovoy A.P. Influence of intermolecular interactions on spectral and photochemical properties of tetraazachlorine derivatives. The thesis for a PhD degree in chemistry. Moscow, 2014. (In Russ.)]
9. Bilgicli A.T., Yarasir M.N., Kandaz M., Ozkaya A.R. H-type aggregation of functional metal ion sensing phthalocyanines: Synthesis, characterization and electrochemistry. Polyhedron, 2010, vol. 29. pp. 2498-2510.
10. Arslan S., Yilmaz I. A new water-soluble metal-free phthalocyanine substituted with naphtoxy-4-sulfonic acid sodium salt. Synthesis, aggregation, electrochemistry and in situ spectroelectrochemistry. Polyhedron, 2007, vol. 26, pp. 2387-2394.
11. Gradova M.A, Zhdanova K.A, Bragina N.A, Lobanov A.V., Mel'nikov M.Ya. Agregacionnoe sostoyanie amfil'nyh kationnyh proizvodnyh tetrafenilporfirina v vodnyh mikrogeterogennyh sistemah. Izv. Akademii nauk. Seriya himicheskaya, 2015, № 4, s. 806-811. [Gradova M.A., Zhdanova K.A., Bragina N.A., Lobanov A.V., Melnikov M.Ya. Russian Chemical Bulletin, 2015, vol. 64, no. 4, pp. 806-811. (In Russ.)]
12. Gradova M.A., Artemov V.V, Lobanov A.V. Aggregation behavior of tatrapheniylporphyrin in aqueous surfactant solutions: Chiral premicellar J-aggregate formation. J. of Porphyrins and Phthalocyanines, 2015, no. 19, pp. 1-7.
