Sevastopol, Sevastopol, Russian Federation
Using experimental titration 1H NMR and DOSY data the ability of Pt (II) complexes to aggregate was investigated. The equations of statistical-thermodynamic model describing aggregation process were derived. Quantitative parameters of self-association of metal complexes were evaluated.
self-association, NMR spectroscopy, diffusion-ordered spectroscopy (DOSY), cyclometallated complexes Pt(II), aggregation number
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