DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION

T A Misharina; M B Terenina; N I Krikunova

UDC

577

DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION

Published in Russian Journal of Biological Physics and Chemisrty · Pages 146–152 · Rubric: MEDICAL BIOPHYSICS AND BIOPHYSICAL CHEMISTRY

Received: 20.03.2018 Accepted: 20.03.2018 Published: 25.03.2018 Language of publication: RUS

Authors

T A Misharina

M B Terenina

N I Krikunova

T A Misharina

Emanuel Institute of Biochemical Physics, Russian Academy of Sciences; Plekhanov Russian Economic University

M B Terenina

Emanuel Institute of Biochemical Physics, Russian Academy of Sciences

N I Krikunova

Emanuel Institute of Biochemical Physics, Russian Academy of Sciences

ABSTRACT

The solid-phase microextraction method in combination with capillary gas-liquid chromatography was used to study the composition of the biologically active components of a mixture of essential oils present in the gas phase above the sample. It was found that the extraction efficiency of volatile substances depended on the composition of the sample, the concentration of essential oils, the properties and structure of volatile compounds, the nature of the polymer sorbent, and the extraction time. The increase in concentration of essential oils in test samples resulted in the increase of sorption of more volatile nonpolar monoterpenes and decrease of sorption of high-boiling acetates and sesquiterpenes. It was found that polydimethylsiloxane had the highest sorption activity and capacity, a mixed polymer of polydimethylsiloxane with carboxene showed the minimal values. The addition of water to a mixture of essential oils led to an increase in the extraction of nonpolar compounds and a decrease in the sorption of polar substances.

KEYWORDS

solid-phase microextraction, capillary gas-liquid chromatography, volatile organic compounds, essential oils

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This work is licensed under Creative Commons Attribution 4.0 International Creative Commons

GOST

Misharina T. A., Terenina M. B., Krikunova N. I. DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION // . 2018. pp. 146-152. (Date of access 20.08.2026).

MLA

T A Misharina, Terenina M. B., Krikunova N. I.. "DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION." (2018): 146-152.

APA

Misharina T. A., Terenina M. B., Krikunova N. I. (2018). DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION. , 146-152.

Chicago

T A Misharina, Terenina M. B., Krikunova N. I.. "DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION." , no. (2018): 146-152.

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{{cite journal | author = Misharina T. A., Terenina M. B., Krikunova N. I. | title = DETERMINATION OF BIOLOGICALLY ACTIVE VOLATILE ORGANIC COMPOUNDS BY SOLID-PHASE MICROEXTRACTION | journal = | year = 2018 | pages = 146-152 }}

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