PHASE TRANSITIONS OF WATER AS A SOURCE OF SLOW OSCILLATORY PROCESSES IN LIQUID MEDIA
Abstract and keywords
Abstract (English):
In the liquid phase of water and aqueous solutions, the presence of transparent spherical structures, their periodic appearance, growth, destruction and reappearance, consistent with fluctuations in the physical-chemical parameters of the liquids under study, was observed. These spheres consist of liquid-crystal water forming "exclusion zones" around hydrophilic colloidal particles. The growth of spheres leads to a decrease in the volume of free water and an increase in the osmotic pressure, which, after reaching a critical value, leads to the destruction of spheres. Thus, all complex dynamics is controlled by phase transitions of water - from free to bound (liquid crystal) state and back. Osmotic pressure acts as an information intermediary and synchronizer of phase transitions in the entire volume of the fluid. Liquid-crystalline aqueous spheres exhibit the properties of a viscous liquid and evaporate at 300 ° C. When the water freezes, they turn into ice balls. The similarity of liquid crystal spheres to "polywater" and "bottom ice" is discussed.

Keywords:
liquid water phases, self-oscillations, dynamics of mesomorphic water structure
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References

1. Maestro L.M., Marqués, M.I., Camarillo, E. [et al.] On the existence of two states in liquid water: impact on biological and nanoscopic systems. Int. J. Nanotechnol., 2016, vol. 13, no 8/9, pp. 667-677.

2. Gallo P., Amann-Winkel K., Angell C.A. [et al.] Water: A Tale of Two Liquids. Chem. Rev., 2016, vol. 116, pp. 7463-7500.

3. Yahno T.A. [i dr.] Novaya tehnologiya issledovaniya mnogokomponentnyh zhidkostey s ispol'zovaniem kvarcevogo rezonatora. Teoreticheskoe obosnovanie i prilozheniya. ZhTF, 2009, t. 79, № 10, s. 22-29. [Yakhno T.A. [et al.] A New technology for studying multicomponent liquids using a quartz crystal resonator: theory and applications. Technical Physics, 2009, vol. 54, no. 10, pp. 1423-1430. (In Russ.)]

4. Yahno T.A., Yahno V.G. «Fenomen kapli kofe» i ego vremennye fluktuacii. Avtonomnye kolebatel'nye processy v kolloidnyh zhidkostyah. ZhTF, 2017, t. 87, № 3, s. 323-330. [Yakhno T.A., Yakhno V.G. The coffee-drop phenomenon and its time fluctuations: self-sustained oscillations in colloidal liquids. Technical Physics, 2017, vol. 62, no. 3, pp. 347-354. (In Russ.)]

5. Yahno T.A., Yahno V.G. Medlennye avtokolebatel'nye processy v kolloidnyh zhidkostyah. Rol' rastvoritelya. Preprint. http://biophys.ru/lib/sci/rhythm/484-rhythm-14 30.11.2016. [Yakhno T.A., Yakhno V.G. Slow self-oscillatory processes in colloidal fluids. Role of the solvent. Preprint, http://biophys.ru/lib/sci/rhythm/484- rhythm-14 30.11.2016. (In Russ.)]

6. Yakhno T.A., Yakhno V.G. Water-induced self-oscillatory processes in colloidal systems by the example of instant coffee. Journal of Basic and Applied Research International, 2017, vol. 20, no. 2, pp. 70-83.

7. Lippincott E.R., Stromberg R.R., Grant W.H., Cessac G.L. Polywater. Science, 1969, vol. 164, pp. 1482-1487.

8. Pollack G. The fourth phase of water: beyond solid, liquid and vapor. Ebner & Sons publisher, Seattle WA, USA, 2013, 357 p, http://www.ivoviz.hu/files/GHP_thefourthphaseofwater.pdf.

9. So E., Stahlberg R., Pollack G.H. Exclusion zone as intermediate between ice and water. WIT Transactions on Ecology and The Environment, 2011, vol. 153, doihttps://doi.org/10.2495/WS110011.

10. Deryagin B.V. Mir kolloidno-poverhnostnyh yavleniy. Vestnik AN SSSR, 1990, t. 9, s. 68-74. [Derjagin B.V. The world of colloid-surface phenomena. Vestnik AN SSSR, 1990, vol. 9, pp. 68-74. (In Russ.)]

11. Zheng J., Chin W-C, Khijniak E. [et al.] Surfaces and interfacial water: Evidence that hydrophilic surfaces have long-range impact. Advances in Colloid and Interface Science, 2006, vol. 127, pp. 19-27, http://courses.washington.edu/bioe555/Zheng.pdf.

12. Deryagin B.V. Novye dannye o sverhplotnoy vode. UFN, 1970, t. 4, s. 726-728. http://ufn.ru/ufn70/ ufn70_4/Russian/r704j.pdf. [Derjagin B.V. New data on superdense water. Physics - Uspekhi, 1970, vol. 13, no. 2, pp. 305-308. http://ufn.ru/ufn70/ufn70_4/Russian/r704j.pdf (In Russ.)]

13. Rousseau D.L., Porto S.P. Polywater: Polymer or Artifact? Science, 1970, vol. 167, no. 3926, pp. 1715-9.

14. Davis R.E., Rousseau D.L., Board R.D. "Polywater:" evidence from electron spectroscopy for chemical analysis (ESCA) of a complex salt mixture. Science, 1971, vol. 171, no. 3967, pp. 167-70.

15. Rousseau D.L. "Polywater" and sweat: similarities between the infrared spectra. Science, 1971, vol. 171, no. 3967, pp. 170-172.


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